Oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans
Jiang-Ling Shi, Ding Wang, Xi-Sha Zhang and 4 more
Nature Communications · 2017
doi:10.1038/s41467-017-00078-6 (opens in a new tab)
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Abstract
Cross-dehydrogenative coupling is finding increasing application in synthesis, but coupling two chemically distinct sites remains a challenge. Here, the authors report an oxidative coupling between sp 2 and sp 3 carbons by sequentially activating the more active aryl site followed by the alkyl position.
Abstract licence: CC BY-NC-ND
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