Skip to content
naulon

No retraction, correction or concern found when last checked on Oct 18, 2026.

Hyperbolic phonon-polaritons in boron nitride for near-field optical imaging and focusing

Peining Li, Martin Lewin, Andrey V. Kretinin and 6 more

Nature Communications · 2015 · CC BY

doi:10.1038/ncomms8507

Abstract

Hyperbolic materials exhibit sub-diffractional, highly directional, volume-confined polariton modes. Here we report that hyperbolic phonon polaritons allow for a flat slab of hexagonal boron nitride to enable exciting near-field optical applications, including unusual imaging phenomenon (such as an enlarged reconstruction of investigated objects) and sub-diffractional focusing. Both the enlarged imaging and the super-resolution focusing are explained based on the volume-confined, wavelength dependent propagation angle of hyperbolic phonon polaritons. With advanced infrared nanoimaging techniques and state-of-art mid-infrared laser sources, we have succeeded in demonstrating and visualizing these unexpected phenomena in both Type I and Type II hyperbolic conditions, with both occurring naturally within hexagonal boron nitride. These efforts have provided a full and intuitive physical picture for the understanding of the role of hyperbolic phonon polaritons in near-field optical imaging, guiding, and focusing applications.

Full text

Its licence does not allow us to show the full text. Read it at PubMed Central:

Read at PubMed Central

References 40

  1. 1.

    Poddubny A., Iorsh I., Belov P. & Kivshar Y. Hyperbolic metamaterials. Nat. Photon. 7, 948–957 (2013 ).

    Not in our library

  2. 2.

    Jacob Z., Alekseyev L. V. & Narimanov E. Optical hyperlens: far-field imaging beyond the diffraction limit. Opt. Express 14, 8247–8256 (2006 ).

    Not in our library10.1364/oe.14.008247

  3. 3.

    Salandrino A. & Engheta N. Far-field subdiffraction optical microscopy using metamaterial crystals: theory and simulations. Phys. Rev. B 74, 075103 (2006 ).

    Not in our library

  4. 4.

    Liu Z., Lee H., Xiong Y., Sun C. & Zhang X. Far-field optical hyperlens magnifying sub-diffraction-limited objects. Science 315, 1686 (2007 ).

    Not in our library10.1126/science.1137368

  5. 5.

    Hoffman A. J. et al. Negative refraction in semiconductor metamaterials. Nat. Mater. 6, 946–950 (2007 ).

    Not in our library10.1038/nmat2033

  6. 6.

    Yao J. et al. Optical negative refraction in bulk metamaterials of nanowires. Science 321, 930 (2008 ).

    Not in our library10.1126/science.1157566

  7. 7.

    Krishnamoorthy H. N. S., Jacob Z., Narimanov E., Kretzschmar I. & Menon V. M. Topological transitions in metamaterials. Science 336, 205–209 (2012 ).

    Not in our library10.1126/science.1219171

  8. 8.

    Ishii S., Kildishev A. V., Narimanov E., Shalaev V. M. & Drachev V. P. Sub-wavelength interference pattern from volume plasmon polaritons in a hyperbolic medium. Las. Photon. Rev. 7, 265–271 (2013 ).

    Not in our library

  9. 9.

    Yang X., Yao J., Rho J., Yin X. & Zhang X. Experimental realization of three-dimensional indefinite cavities at the nanoscale with anomalous scaling laws. Nat. Photon. 6, 450–454 (2012 ).

    Not in our library

  10. 10.

    Caldwell J. D. et al. Sub-diffraction, volume-confined polaritons in the natural hyperbolic material: hexagonal boron nitride. Nat. Commun. 5, 5221 (2014 ).

    Not in our library10.1038/ncomms6221

  11. 11.

    Dai S. et al. Tunable phonon polaritons in atomically thin van der Waals crystals of boron nitride. Science 343, 1125–1129 (2014 ).

    Not in our library10.1126/science.1246833

  12. 12.

    Prokes S.M. et al. Hyperbolic and plasmonic properties of silicon/Ag aligned nanowire arrays. Opt. Express 21, 14962–14974 (2013 ).

    Not in our library10.1364/oe.21.014962

  13. 13.

    Khurgin J. B & Boltasseva A. Reflecting upon the losses in plasmonics and metamaterials. MRS Bull 37, 768–779 (2012 ).

    Not in our library

  14. 14.

    West P. R. et al. Searching for better plasmonic materials. Las. Photon. Rev 4, 795–808 (2010 ).

    Not in our library

  15. 15.

    Tassin P., Koschny T., Kafesaki M. & Soukoulis C. M. A comparison of graphene, superconductors and metals as conductors for metamaterials and plasmonics. Nat. Photon. 6, 259–264 (2012 ).

    Not in our library

  16. 16.

    Hillenbrand R., Taubner T. & Keilmann F. Phonon-enhanced light–matter interaction at the nanometre scale. Nature 418, 159–162 (2002 ).

    Not in our library10.1038/nature00899

  17. 17.

    Caldwell J. D. et al. Low-loss, infrared and terahertz nanophotonics using surface phonon polaritons. Nanophotonics 4, 44–68 (2015 ).

    Not in our library

  18. 18.

    Caldwell J. D. et al. Low-loss, extreme sub-diffraction photon confinement via silicon carbide surface phonon polariton nanopillar resonators. Nano Lett. 13, 3690–3697 (2013 ).

    Not in our library10.1021/nl401590g

  19. 19.

    Wang T., Li P., Hauer B., Chigrin D. N. & Taubner T. Optical properties of single infrared resonant circular microcavities for surface phonon polaritons. Nano Lett. 13, 5051–5055 (2013 ).

    Not in our library10.1021/nl4020342

  20. 20.

    Chen Y. et al. Spectral tuning of localized surface phonon polariton resonators for low-loss mid-ir applications. ACS Photon. 1, 718–724 (2014 ).

    Not in our library

  21. 21.

    Xu X. G. et al. One-dimensional surface phonon polaritons in boron nitride nanotubes. Nat. Commun. 5, 4782 (2014 ).

    Not in our library10.1038/ncomms5782

  22. 22.

    Da Silva R. E. et al. Far-infrared slab lensing and subwavelength imaging in crystal quartz. Phy. Rev. B 86, 155152 (2012 ).

    Not in our library

  23. 23.

    Fonoberov V. A. & Balandin A. A. Polar optical phonons in wurtzite spheroidal quantum dots: theory and application to ZnO and ZnO/MgZnO nanostructures. J. Phys. Condens. Matter 17, 1085–1097 (2005 ).

    Not in our library

  24. 24.

    Thompson D. W., De Vries M. J., Tiwald T. E. & Woollam J. A. Determination of optical anisotropy in calcite from ultraviolet to mid-infrared by generalized ellipsometry. Thin Solid Films 313, 341–346 (1998 ).

    Not in our library

  25. 25.

    Sun J., Litchinitser N. M. & Zhou J. Indefinite by nature: from ultraviolet to terahertz. ACS Photon. 1, 293–303 (2014 ).

    Not in our library

  26. 26.

    Zhang Y., Fluegel B. & Mascarenhas A. Total negative refraction in real crystals for ballistic electrons and light. Phys. Rev. Lett. 91, 157404 (2003 ).

    Not in our library10.1103/physrevlett.91.157404

  27. 27.

    Chen X. L., He M., Du Y. X., Wang W. Y. & Zhang D. F. Negative refraction: an intrinsic property of uniaxial crystals. Phys. Rev. B 72, 113111 (2005 ).

    Not in our library

  28. 28.

    Geick R., Perry C. H. & Rupprecht G. Normal modes in hexagonal boron nitride. Phy. Rev. B 146, 543–547 (1966 ).

    Not in our library

  29. 29.

    Pendry J. B. Negative refraction makes a perfect lens. Phys. Rev. Lett. 85, 3966–3969 (2000 ).

    Not in our library10.1103/physrevlett.85.3966

  30. 30.

    Fang N. et al. Sub-diffraction-limited optical imaging with a silver superlens. Science 308, 534–537 (2005 ).

    Not in our library10.1126/science.1108759

  31. 31.

    Taubner T., Korobkin D., Urzhumov Y., Shvets G. & Hillenbrand R. Near-field microscopy through a SiC superlens. Science 313, 1595 (2006 ).

    Not in our library10.1126/science.1131025

  32. 32.

    Wueppen J., Jungbluth B., Taubner T. & Loosen P. Ultrafast tunable mid IR source. in Infrared, Millimeter and Terahertz Waves (IRMMW-THz), 36th-International Conference, IEEE, 1–2 (2011 ).

    Not in our library

  33. 33.

    Bensmann S. et al. Near-field imaging and spectroscopy of locally strained GaN using an IR broadband laser. Opt. Express 22, 22369–22381 (2014 ).

    Not in our library10.1364/oe.22.022369

  34. 34.
  35. 35.

    Taubner T., Keilmann F. & Hillenbrand R. Nanoscale-resolved subsurface imaging by scattering-type near-field optical microscopy. Opt. Express 13, 8893–8899 (2005 ).

    Not in our library10.1364/opex.13.008893

  36. 36.

    Li P., Wang T., Bockmann H. & Taubner T. Graphene-enhanced infrared near-field microscopy. Nano Lett 14, 4400–4405 (2014 ).

    Not in our library10.1021/nl501376a

  37. 37.

    Geim A. K. & Grigorieva I. V. Van der Waals heterostructures. Nature 499, 419–425 (2013 ).

    Not in our library10.1038/nature12385

  38. 38.

    Taniguchi T. & Watanabe K. Synthesis of high-purity boron nitride single crystals under high pressure by using Ba-BN solvent. J. Cryst. Growth 303, 525–529 (2007 ).

    Not in our library

  39. 39.

    Watanabe K., Taniguchi T. & Kanda H. Direct-bandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal. Nat. Mater. 3, 404–409 (2004 ).

    Not in our library10.1038/nmat1134

  40. 40.

    Kretinin A. V. et al. Electronic Properties of graphene encapsulated with different two-dimensional atomic crystals. Nano Lett. 14, 3270–3276 (2014 ).

    Not in our library10.1021/nl5006542

Cited by papers we hold 5

Reads

Read by people on this page

None yet.

Checked or read by AI through naulon

None yet.

A person counts once a day per paper. We keep no cookie and no address: a reader is a hash that changes every day. Any month under five reads shows no number.

Are you an author?

Is this your paper?

Claim it to add your note and be paid when agents cite it. Free.