Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
Anne-Frédérique Pécharman, Annie L. Colebatch, Michael S. Hill and 3 more
Nature Communications · 2017
doi:10.1038/ncomms15022 (opens in a new tab)
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Abstract
Organoboranes are widely employed in organic synthesis and typically are prepared using electrophilic boron sources. Here the authors report a route to nucleophilic boryl anions via organomagnesium-driven cleavage of boron-boron bonds.
Abstract licence: CC BY-NC-ND
References55
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