Competitive solvent-molecule interactions govern primary processes of diphenylcarbene in solvent mixtures
Johannes Knorr, Pandian Sokkar, Sebastian Schott and 5 more
Nature Communications · 2016
doi:10.1038/ncomms12968 (opens in a new tab)
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Abstract
Photochemistry in solution often involves coexisting reaction channels that may comprise intermediates capturing a solvent molecule. Here, the authors show for one of the most reactive species, diphenylcarbene, that the decision-maker is not the nearest solvent molecule but its neighbour.
Abstract licence: CC BY-NC-ND
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