Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
Yoshiaki Shoji, Naoki Tanaka, Sho Muranaka and 5 more
Nature Communications · 2016
doi:10.1038/ncomms12704 (opens in a new tab)
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Abstract
Coupling reactions to form C–C bonds typically require transition metals. Here the authors report that an organoboron compound can allow sequential alkyne insertion and unusual oxidative deborylation/Csp2 –Csp2 coupling, enabling the transformation of acetylenes into extended π-conjugated molecules.
Abstract licence: CC BY-NC-ND
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