Diagenetic alteration of magnetic minerals in Labrador Sea sediments (IODP Sites U1305, U1306, and U1307)

In order to reveal the potential effects of early diagenesis on magnetic minerals in deep‐sea sediments, we studied early diagenetic zones and magnetic mineral characteristics of Lower Pliocene hemipelagic sediment samples from IODP Sites U1305, U1306, and U1307 on Eirik Drift, Labrador Sea. All samples analyzed were unlithified silty clay sediments recovered by a piston corer from depths down to 200 meters composite depth (mcd). Based on shipboard interstitial‐water geochemistry, we divided the sediment column from each site into six early diagenetic zones. Magnetite (Fe3O4) was present at all analyzed depths, whereas maghemite (γFe2O3) was found only above the iron reduction zone. We attribute this to associated changes in interstitial redox conditions, which induced preferential dissolution of maghemitized surfaces on magnetite grains. Mineral magnetic results indicate a general down‐hole change in mean grain size of magnetic minerals. At Site U1307, which has relatively low organic carbon contents, the diagenetic zones occur at greater depths than at the other studies sites. This suggests that interstitial oxygen levels at this site remained high enough to degrade organic matter through oxic bacterial activity, and that detrital magnetic minerals have been preserved even at depth.

Abstract licence: CC BY-ND

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