Synthesis of New Indolizidine Derivatives from 1‑(2-Quinolyl)-2-propen-1-ol
Donatella Giomi, Jacopo Ceccarelli, Alberto Brandi
ACS Omega · 2018
doi:10.1021/acsomega.8b00167 (opens in a new tab)
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Abstract
The four-step procedure involving bromination, reduction, and nucleophilic substitution via elimination/addition previously applied to 1-(2-pyridyl)-2-propen-1-ol for the synthesis of indolizidine systems has now been extended to 1-(2-quinolyl)-2-propen-1-ol allowing a general access to benzo-fused derivatives. For instance, (±)-benzo[e]lentiginosine has been easily synthesized in an 18% overall yield.
Abstract licence: CC BY-NC-ND
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