Influence of niobium microalloying on the thermal stability of medium-carbon carbide-free bainitic steel

This paper investigates the influence of niobium on the thermal stability of ultra-fine bainite microstructures and their mechanical properties by means of an isothermal transformation at 340 °C, followed by tempering in the range of 200–700 °C for two medium-carbon, carbide-free bainitic steels with and without 0.018 wt. % Nb. The results reveal that ultra-fine bainite microstructures, especially film-like retained austenite, is refined, and the average carbon content of retained austenite is also improved as a result of the addition of Nb element. Both of the bainitic steels in this paper exhibit good thermal stability at low temperatures (≤400 °C) and precipitation hardening arising from carbide precipitation following tempering at 500 °C. The precipitation strengthening compensates for the decrease in strength induced by the decrement in the dislocation density and coarsening of the bainitic ferrite plates during tempering process. M23C6- and MC-type carbides are precipitated in Nb-free and Nb steels, respectively, when the tempering temperature exceeds 400 °C. The further coarsening of the carbides and bainitic ferrite plates, and the decrement in the dislocation density in the latter, relate to the decrease in the mechanical properties for both of the tested bainitic steels following tempering at 500 and 600 °C. Compared to those in the bainitic steel without Nb, the larger size and superior thermal stability of MC-type carbides results in greater strength and elongation of the bainitic steel containing 0.018 wt. % of the Nb element, but does harm to its impact toughness after tempering at 700 °C.

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