Measurement of equilibrium potential of Cl2/Cl− redox couple in molten chlorides
Zujian Tang, Qilin Yuan, Shangping Zhu and 2 more
Electrochemistry Communications · 2025
doi:10.1016/j.elecom.2025.107980 (opens in a new tab)
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Abstract
The current interruption method is used to determine the equilibrium potential of the Cl2/Cl− redox couple, and the theory behind the measurement is discussed. Different AgCl/Ag reference electrodes are prepared and calibrated by measuring the equilibrium potential of Cl2/Cl− redox couple. Cyclic voltammograms against the different AgCl/Ag reference electrodes before and after calibration in pure lithium chloride are reported, showing good agreement with thermodynamic calculations.
Abstract licence: CC BY-NC
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