A strategy combining the catalytic cracking of C6-C8 olefins and methanol to olefins (MTO) reaction through SAPO-34 pre-coking
Yanfen Zuo, Yunpeng Zhang, Qiang Ren and 3 more
Catalysis Communications · 2022
doi:10.1016/j.catcom.2022.106461 (opens in a new tab)
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Abstract
The coupling conversion of C6-C8 olefins and methanol over SAPO-34 is proposed for enhancing carbon resource utilization and light olefins production. With the aid of thermogravimetric analysis (TGA), dissolution-extraction experiment and molecular dynamics simulations, the relationship between reactive “coke” and reaction pathway of methanol-to-olefin (MTO) are studied. Owing to its remarkable product shape selectivity, octene is explored to be an effective coking source for promoting ethene production.
Abstract licence: CC BY-NC
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