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Nanoporous Organic Polymer/Cage Composite Membranes

Alexandra F. Bushell, Peter M. Budd, Martin P. Attfield and 7 more

Angewandte Chemie International Edition · 2012

doi:10.1002/anie.201206339

Abstract

Organic–organic composite membranes are prepared by in situ crystallization of cage molecules in a polymer of intrinsic microporosity. This allows a direct one-step route to mixed-matrix membranes, starting with a homogeneous molecular solution. Extremely high gas permeabilities are achieved, even after ageing for more than a year, coupled with good selectivity for applications such as CO2 recovery.

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